We show that solar $\gamma$-ray observations can provide a complementary probe of Dark Matter in scenarios where the interactions with the Standard Model proceed via long-lived mediators. For illustration we consider a simplified model which provides solar $\gamma$-ray
fluxes observable with the next generation $\gamma$-ray telescopes, while complying with the existing experimental constraints. Our results suggest that solar $\gamma$-ray fluxes can be orders of magnitude larger than the ones from the Galactic center, while being subject to low backgrounds.